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Fluorosilicone Oil & Fluorosilicone Rubber: Oil Resistance, Cold Flexibility, and Grade Selection in One Read

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Question 1: What's the difference between fluorosilicone oil and regular silicone oil — and why is it a must-have for fuel and solvent environments?

Answer: Fluorosilicone oil is a modified silicone fluid whose siloxane side chains carry γ-trifluoropropyl groups (–CH₂CH₂CF₃). The common reactive forms are hydroxyl-terminated (MY 25O), hydrogen-terminated (MY 25H), and vinyl-terminated (MY 25V). The essential difference from ordinary dimethyl silicone fluid is what the polar fluorine atoms bring:

  • Ordinary methyl silicone fluid swells heavily or is extracted out of fuels, lubricating oils, and aromatic solvents and fails; once trifluoropropyl is introduced, the fluid stays stable in aliphatic/aromatic fuels, mineral lubricants, hydraulic oils, and certain synthetic oils at both room and elevated temperature. It is currently the only non-polar elastomer raw-material system that works long-term in fuel media from −68 to 232 °C;
  • Meanwhile it keeps every advantage of the siloxane backbone: low viscosity–temperature coefficient, low surface tension, high flash point, low pour point, long-term service from −50 °C to 250 °C, plus chemical and physiological inertness.

In short, the value of fluorosilicone oil isn't "cheap" — it's "it holds up where ordinary silicone oil can't." When selecting, check the fluorine content first (up to 100% for homopolymers, adjustable from 10%–90% for copolymers), then match viscosity and end-group functionality to your curing chemistry.

Question 2: Just how good is the oil/cold resistance? Can it replace FKM fluoroelastomer?

Answer: Let's look scenario by scenario (based on measured data of commercially available grades):



Conclusion: Replacing FKM depends on the conditions — in the "cold + fuel/solvent" crossover duty cycle, fluorosilicone clearly wins: below −50 °C FKM stiffens and loses elasticity while fluorosilicone gum stays flexible, and its swelling in methanol-gasoline is far lower than FKM's, making it ideal for aircraft integral-tank seals, automotive shaft seals/diaphragms, and fuel-pump diaphragms. But on pure heat resistance and aggressive media, FKM still leads (fluorosilicone tops out around 250 °C and decomposes with toxic gas evolution above 300 °C). Two more points customers must know: ① fluorosilicone rubber is a difficult-to-bond material (low surface energy — plasma treatment or primer is required for secondary bonding); ② the compound structures during storage (gel content rises), so it must be re-milled moderately before use — over-milling drops molecular weight and leaves the gum tacky and scrapped. 

Antistatic precipitated silicone rubber, plz check MY HTV 336 series

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